Electrochemical Discovery Laboratory
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Role of Structural Hydroxyl Groups in Enhancing Performance of Electrochemically-Synthesized Bilayer V2O5
Structural OH species, an intrinsic feature of electrochemically-synthesized V2O5 (EC-V2O5), are highly thermally and electrochemically stable and are responsible for the improved cycle life and reversible capacity of these materials for beyond-lithium-ion systems. Read More
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The Electrochemical Discovery Laboratory
The Electrochemical Discovery Laboratory (EDL) — a key JCESR discovery tool located at Argonne — synthesizes high-quality materials for testing in beyond-lithium-ion batteries and characterizes their properties with state-of-the-art analytical techniques. Read More
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Water as a Catalyst – Improving how Batteries Function
Anyone who has ever dropped a cell phone in the sink will tell you that electrical devices and water do not go together. However, a new study has shown that conventional wisdom may not hold on the molecular scale in some beyond-lithium-ion batteries. Read More
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Promising Directions and the Tools to Get Us There
At the halfway point in our five-year charter, we have narrowed our research directions within the three promising energy storage concepts we are pursuing: multivalent intercalation, chemical transformation, non-aqueous redox flow. In converging these directions to proof-of-concept prototypes, we make extensive use of JCESR’s distinguishing tools. Read More
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Trace Water Catalyzes Lithium Peroxide Electrochemistry
Water at ppm levels catalyzes the conversion of lithium superoxide (LiO2) to lithium peroxide (Li2O2) by the reaction cycle shown. Because water is not consumed in the cycle, trace amounts leverage large effects. Read More
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EDL: Discovering Electrochemistry at Atomic and Molecular Levels
Established in situ Electrochemical Discovery Lab (EDL) for systematic studies of wet and dry interfaces for materials-by-design and electrolytes-by-design at atomic and molecular levels Read More
Latest Updates
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A Message from JCESR Director George Crabtree
Despite the coronavirus challenges, JCESR continues to push the frontier of energy storage science as we telecommute from home, like much of the nation. We are turning our attention to computation, data analysis and paper writing which continues at a normal or higher pace, enabled … Read More
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You’re invited: Idaho National Laboratory and JCESR webinar on energy storage (March 18 )
Electrification is changing the energy landscape of the Mountain West region. While energy storage remains a key enabler to this transformation, infrastructure upgrade and supply chain development will be a key driver for this new economy. Join us on March 18 for a webinar where we’ll … Read More
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Direct Nano-Synthesis Methods Notably Benefit Mg-Battery Cathode Performance
A novel Mg cathode material – CuCo2S4 – was identified as a conversion material where direct nano-synthesis was required to provide the best electrochemical performance and deliver 350 mAh·g-1 at 60 °C, a capacity nearly double that of ball-milled material with similar dimensions. Read More
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Quantifying Capacity Losses due to Solid Electrolyte Interphase Evolution
We quantified the capacity loss originating in solid electrolyte interphase (SEI) growth during each cycle and extracted the proportionality constant for SEI growth following a parabolic growth law. This continuous SEI growth contributes to the increasing overpotential, leading to capacity fading at a given constant … Read More
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On Lifetime and Cost of Redox-Active Organics for Aqueous Flow Batteries
In this viewpoint, we recommend methodology for (1) testing aqueous organic flow batteries to better understand the fade mechanisms and failure modes, and for (2) techno-economic assessment of these batteries that incorporates the costs associated with electrolyte decay and replacement to articulate a feasible design … Read More
