As JCESR scientists work to develop lighter and less expensive chemistries than those used in current lithium-ion batteries, lithium-sulfur shows tremendous promise. However, current lithium-sulfur batteries require an excessive amount of electrolyte to achieve moderate cycle life. This perspective presents an alternate approach of using “sparingly solvating” electrolytes, which could move us closer to long-lived, high energy density lithium-sulfur batteries.
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Toward the Development of a High-VoltageMg Cathode Using a Chromium Sulfide Host
The electrochemical behavior of MgM2S4 (M = Ti, Cr) thiospinels was investigated experimentally and their redox activity was understood through analysis of the computed electronic density of states. Read More
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Understanding and enhancing ion transport in a systematic series of polyacetal electrolytes
Polyacetal electrolytes can electrochemically outperform the well-established poly(ethylene oxide) systems used in Li-ion batteries. In this work, we employ a suite of experimental and theoretical techniques to reveal the underlying molecular interactions between cations, anions and the polyacetal host that lead to improved electrochemical efficacy. Read More
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A Comparative Study of Organic Radical Cation Stability and Coulombic Efficiency for Nonaqueous Redox Flow Battery Applications
The charged forms of high oxidation potential posolytes exhibited either self-discharge or a combination of self-discharge and molecular degradation, limiting CE and/or cycle lifetime in the galvanostatic cycling, presenting a challenge of utilizing high potential compounds in nonaqueous RFBs. Read More
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Employing the Dynamics of the Electrochemical Interface at Aqueous Zinc-Ion Battery Cathode
This report illustrates how dissolution, once seen as a fundamental drawback for MnO2 cathodes, can fortify capacity in AZIBs and provides guidance for expanding this concept and developing other systems that can reversibly deposit and dissolve the active material in a dynamic manner. Read More
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Understanding of electrolyte solution chemistry and interface electrochemistry of divalent metal batteries
This review discusses the design of electrolytes that involve different solvation structures related, in particular, the choice of anionic species. It focuses on the dynamic interplay of these electrolytes with interfaces as well as the electrochemistry of divalent metal anodes. Read More
