Scientific Achievement
- Directly observed a sequence of interconnected electrolyte degradation mechanisms to evaluate stability and degradation in battery electrolytes
- Developed a rapid method using STEM to evaluate stability and degradation in battery electrolytes
Significance and Impact
- Using liquid stages in the STEM, it is possible to monitor dynamic processes during Li-ion battery operation at high spatial resolution
- This in-situ approach can be used to scan new libraries of electrolytes to rapidly develop and identify next-generation electrolytes
- This approach could aid a systematic study of electrolyte degradation for any controlled/quantitative in operando liquid stage experiment in the STEM for battery research
Research Details
- Explored five different electrolytes commonly used for Li-ion and Li-air battery applications using in-situ liquid STEM
- Identified conditions for highly stable electrolytes against the electron beam
Work performed at Pacific Northwest National Laboratory (JCESR partner), UC-Davis and Florida State University. P. Abellán, B.L. Mehdi, L.R. Parent, M. Gu, C. Park, W. Xu, Y. Zhang, I. Arslan, J-G Zhang, C. Wang, J.E. Evans, N.D. Browning. Nano Letters, 2014.
DOI: 10.1021/nl404271k