Assessing the levelized cost of vanadium redox flow batteries with capacity fade and rebalancing

Top: Example of the simulated VRFB capacity retention as a function of time annotated with the respective model steps. Bottom: Levelized cost of storage (LCOS) as a function of lower capacity limit, showing the effect that rebalancing schedule has on maintenance costs and thus LCOS.

Scientific Achievement

Levelized cost is an important assessment metric that should be considered in addition to capital cost when determining the potential value of battery systems. Here, we contemplate the vanadium redox flow battery (VRFB) whose symmetric chemistry and open architecture enable periodic system maintenance (e.g. rebalancing) which, in turn, adds economic value.

Significance and Impact

The modeling framework developed provides a systematic means of evaluating and optimizing VRFB operation and maintenance throughout its lifetime, allowing for practical considerations such as capacity sizing, materials selection, rebalancing schedule, and financing schemes.  This tool is flexible and can be extended to nonaqueous RFB chemistries of interest to JCESR.

Research Details

  • There are tradeoffs to consider between increases in upfront costs and decreases in operating costs (or vice versa). The upfront and long-term costs provide different sets of information necessary for economic valuation.
  • The vanadium electrolyte leasing scheme shows promise, as it has the potential to lower both upfront and levelized costs.

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DOI: 10.1016/j.jpowsour.2020.227958

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