Charge Transfer at Dynamic Interfaces
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Incorporating Solvate and Solid Electrolytes for All-Solid-State Li2S Batteries with High Capacity and Long Cycle Life
Incorporating highly concentrated solvate electrolyte into all‐solid‐state Li2S batteries significantly improves the battery performance compared to its bare counterpart. The origin of the improved battery cyclability is the favorable interfacial contact, where the ion conducting network surrounding the active material remains intact even after the significant volume contraction of the Li2S cathode. Read More
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Understanding Ca Electrodeposition and Speciation Processes in Nonaqueous Electrolytes for Next-Generation Ca-Ion Batteries
Rechargeable Ca batteries have attracted little interest due to the extreme difficulty to perform reversible Ca electrodeposition. There is currently only one electrolyte, Ca(BH4)2 in THF, that exhibits reversible Ca deposition at room temperature. However, the underlying deposition mechanism and the interaction of Ca2+ ions with the surrounding molecules are still mostly unknown. Our research explores Ca deposition and speciation processes by using electrochemical and physical characterization techniques. Read More
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Advanced Continuum Models for Simulations of Electrified Interfaces
Development of a novel formalism and methodology to model electrolyte composition at electrified (electrode) interfaces. Predictions that minor species (from the bulk perspective) may become dominant at the electrified interface. Read More
Latest Updates
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You’re Invited - JCESR and Beyond: Translating the Basic Science of Batteries
Please join us at Argonne National Laboratory on Tuesday, April 4, 2023 for JCESR and Beyond: Translating the Basic Science of Batteries. Registration is now open. This in-person event will celebrate 10 years of research from the Joint Center… Read More
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A Message from JCESR: In Memory of George Crabtree
It is with heavy hearts that we say goodbye to George Crabtree, a Senior Scientist and Distinguished Fellow at Argonne National Laboratory, and Director of the Joint Center for Energy Storage Research (JCESR), who passed away unexpectedly on January 23. Dr. Read More
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Cyanopyridines As Extremely Low-Reduction-Potential Anolytes for Nonaqueous Redox Flow Batteries
Discovery of a cyanophenylpyridine derivative with a very low reduction potential and good stability during cycling. Read More
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Characterizing Redoxmer – Electrode Kinetics Using a SECM-Based Spot Analysis Method
Identified asymmetries in electron transfer (ET) kinetics between the reduction and oxidation of ferrocene-based redoxmers by measuring the ET rate constants (kf/kb) as a function of electrode potential. Read More
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Benzotriazoles as Low Potential Anolytes for Non-Aqueous Redox Flow Batteries
We developed an easy-to-synthesize benzotriazole-based anolyte with a high energy redox potential (-2.3 V vs Fc/Fc+) and high solubility that demonstrates stable electrochemical cycling performance. Read More